Standard electrode potential (data page)
The data below tabulates standard electrode potentials (E°), in volts relative to the standard hydrogen electrode, at:
- Temperature 298.15 K (25.00 °C; 77.00 °F);
- Effective concentration 1 mol/L for each aqueous or amalgamated (mercury-alloyed) species;
- Unit activity for each solvent and pure solid or liquid species; and
- Absolute partial pressure 101.325 kPa (1.00000 atm; 1.01325 bar) for each gaseous reagent — the convention in most literature data but not the current standard state (100 kPa).
The Nernst equation adjusts for general concentrations, pressures, or temperatures.
Simultaneous half-reactions do not in general add voltages, but instead add Gibbs free energy change: the product of the voltage and the number of electrons transferred, typically the Faraday constant. For example, from Fe2+ + 2 e− ⇌ Fe(s) (–0.44 V), the energy to create one neutral atom of Fe(s) from one Fe2+ ion and two electrons is 2 × 0.44 eV = 0.88 eV, or 84 895 J/(mol e−). That value is also the standard formation energy for an Fe2+ ion, since e− and Fe(s) both have zero formation energy.
Data from different sources may cause table inconsistencies. For example: Additivity of Gibbs energy implies not the experimental 0.159 V.
Table of standard electrode potentials
[edit]Legend: (s) – solid; (l) – liquid; (g) – gas; (aq) – aqueous (default for all charged species); (Hg) – amalgam; bold – water electrolysis equations.
Element | Half-reaction | E° / V | Electrons | |||
---|---|---|---|---|---|---|
Oxidant | ⇌ | Reductant | ||||
Sr | Sr+ + e− |
⇌ | Sr(s) | -4.101 | 1 | |
Ca | Ca+ + e− |
⇌ | Ca(s) | -3.8 | 1 | |
Th | Th4+ + e− |
⇌ | Th3+ |
-3.6 | 1 | |
Pr | Pr3+ + e− |
⇌ | Pr2+ |
-3.1 | 1 | |
N | 3N 2(g) + 2 H+ + 2 e− |
⇌ | 2HN 3(aq) |
-3.09 | 2 | |
Li | Li+ + e− |
⇌ | Li(s) | -3.0401 | 1 | |
N | N 2(g) + 4H2O + 2 e− |
⇌ | 2NH 2OH(aq) + 2 OH− |
-3.04 | 2 | |
Cs | Cs+ + e− |
⇌ | Cs(s) | -3.026 | 1 | |
Ca | Ca(OH) 2 + 2 e− |
⇌ | Ca(s) + 2 OH− | -3.02 | 2 | |
Er | Er3+ + e− |
⇌ | Er2+ |
-3 | 1 | |
Ba | Ba(OH) 2 + 2 e− |
⇌ | Ba(s) + 2 OH− | -2.99 | 2 | |
Rb | Rb+ + e− |
⇌ | Rb(s) | -2.98 | 1 | |
K | K+ + e− |
⇌ | K(s) | -2.931 | 1 | |
Ba | Ba2+ + 2 e− |
⇌ | Ba(s) | -2.912 | 2 | |
La | La(OH) 3(s) + 3 e− |
⇌ | La(s) + 3 OH− | -2.9 | 3 | |
Fr | Fr+ + e− |
⇌ | Fr(s) | -2.9 | 1 | |
Sr | Sr2+ + 2 e− |
⇌ | Sr(s) | -2.899 | 2 | |
Sr | Sr(OH) 2 + 2 e− |
⇌ | Sr(s) + 2 OH− | -2.88 | 2 | |
Ca | Ca2+ + 2 e− |
⇌ | Ca(s) | -2.868 | 2 | |
Li | Li+ + C 6(s) + e− |
⇌ | LiC 6(s) |
-2.84 | 1 | |
Eu | Eu2+ + 2 e− |
⇌ | Eu(s) | -2.812 | 2 | |
Ra | Ra2+ + 2 e− |
⇌ | Ra(s) | -2.8 | 2 | |
Ho | Ho3+ + e− |
⇌ | Ho2+ | -2.8 | 1 | |
Bk | Bk3+ + e− |
⇌ | Bk2+ |
-2.8 | 1 | |
Yb | Yb2+ + 2 e− |
⇌ | Yb(s) | -2.76 | 2 | |
Na | Na+ + e− |
⇌ | Na(s) | -2.71 | 1 | |
Mg | Mg+ + e− |
⇌ | Mg(s) | -2.7 | 1 | |
Nd | Nd3+ + e− |
⇌ | Nd2+ |
-2.7 | 1 | |
Mg | Mg(OH) 2 + 2 e− |
⇌ | Mg(s) + 2 OH− | -2.69 | 2 | |
Sm | Sm2+ + 2 e− |
⇌ | Sm(s) | -2.68 | 2 | |
Be | Be 2O2− 3 + 3H2O + 4 e− |
⇌ | 2Be(s) + 6 OH− | -2.63 | 4 | |
Pm | Pm3+ + e− |
⇌ | Pm2+ |
-2.6 | 1 | |
Dy | Dy3+ + e− |
⇌ | Dy2+ |
-2.6 | 1 | |
No | No2+ + 2 e− |
⇌ | No | -2.5 | 2 | |
Hf | HfO(OH) 2 + H2O + 4 e− |
⇌ | Hf(s) + 4 OH− | -2.5 | 4 | |
Th | Th(OH) 4 + 4 e− |
⇌ | Th(s) + 4 OH− | -2.48 | 4 | |
Md | Md2+ + 2 e− |
⇌ | Md | -2.4 | 2 | |
Tm | Tm2+ + 2 e− |
⇌ | Tm(s) | -2.4 | 2 | |
La | La3+ + 3 e− |
⇌ | La(s) | -2.379 | 3 | |
Y | Y3+ + 3 e− |
⇌ | Y(s) | -2.372 | 3 | |
Mg | Mg2+ + 2 e− |
⇌ | Mg(s) | -2.372 | 2 | |
Sc | ScF3(aq) + 3 H+ + 3 e− | ⇌ | Sc(s) + 3HF(aq) | -2.37 | 3 | |
Zr | ZrO(OH) 2(s) + H2O + 4 e− |
⇌ | Zr(s) + 4 OH− | -2.36 | 4 | |
Pr | Pr3+ + 3 e− |
⇌ | Pr(s) | -2.353 | 3 | |
Ce | Ce3+ + 3 e− |
⇌ | Ce(s) | -2.336 | 3 | |
Er | Er3+ + 3 e− |
⇌ | Er(s) | -2.331 | 3 | |
Ho | Ho3+ + 3 e− |
⇌ | Ho(s) | -2.33 | 3 | |
Al | H 2AlO− 3 + H2O + 3 e− |
⇌ | Al(s) + 4 OH− | -2.33 | 3 | |
Nd | Nd3+ + 3 e− |
⇌ | Nd(s) | -2.323 | 3 | |
Tm | Tm3+ + 3 e− |
⇌ | Tm(s) | -2.319 | 3 | |
Al | Al(OH) 3(s) + 3 e− |
⇌ | Al(s) + 3 OH− | -2.31 | 3 | |
Sm | Sm3+ + 3 e− |
⇌ | Sm(s) | -2.304 | 3 | |
Fm | Fm2+ + 2 e− | ⇌ | Fm | -2.3 | 2 | |
Am | Am3+ + e− |
⇌ | Am2+ |
-2.3 | 1 | |
Dy | Dy3+ + 3 e− |
⇌ | Dy(s) | -2.295 | 3 | |
Lu | Lu3+ + 3 e− |
⇌ | Lu(s) | -2.28 | 3 | |
Sc | ScF+ 2 + 2 H+ + 3 e− |
⇌ | Sc(s) + 2HF(l) | -2.28 | 3 | |
Tb | Tb3+ + 3 e− |
⇌ | Tb(s) | -2.28 | 3 | |
Gd | Gd3+ + 3 e− |
⇌ | Gd(s) | -2.279 | 3 | |
H | H 2(g) + 2 e− |
⇌ | 2H− |
-2.23 | 2 | |
Es | Es2+ + 2 e− |
⇌ | Es(s) | -2.23 | 2 | |
Pm | Pm2+ + 2 e− |
⇌ | Pm(s) | -2.2 | 2 | |
Tm | Tm3+ + e− |
⇌ | Tm2+ | -2.2 | 1 | |
Dy | Dy2+ + 2 e− |
⇌ | Dy(s) | -2.2 | 2 | |
Ac | Ac3+ + 3 e− |
⇌ | Ac(s) | -2.2 | 3 | |
Yb | Yb3+ + 3 e− |
⇌ | Yb(s) | -2.19 | 3 | |
Cf | Cf2+ + 2 e− |
⇌ | Cf(s) | -2.12 | 2 | |
Nd | Nd2+ + 2 e− |
⇌ | Nd(s) | -2.1 | 2 | |
Ho | Ho2+ + 2 e− |
⇌ | Ho(s) | -2.1 | 2 | |
Sc | Sc3+ + 3 e− |
⇌ | Sc(s) | -2.077 | 3 | |
Al | AlF3− 6 + 3 e− |
⇌ | Al(s) + 6F− |
-2.069 | 3 | |
Cm | Cm3+ + 3 e− |
⇌ | Cm(s) | -2.04 | 3 | |
Pu | Pu3+ + 3 e− |
⇌ | Pu(s) | -2.031 | 3 | |
Pr | Pr2+ + 2 e− |
⇌ | Pr(s) | -2 | 2 | |
Er | Er2+ + 2 e− |
⇌ | Er(s) | -2 | 2 | |
Eu | Eu3+ + 3 e− |
⇌ | Eu(s) | -1.991 | 3 | |
Lr | Lr3+ + 3 e− |
⇌ | Lr | -1.96 | 3 | |
Cf | Cf3+ + 3 e− |
⇌ | Cf(s) | -1.94 | 3 | |
Es | Es3+ + 3 e− |
⇌ | Es(s) | -1.91 | 3 | |
Pa | Pa4+ + e− |
⇌ | Pa3+ |
-1.9 | 1 | |
Am | Am2+ + 2 e− |
⇌ | Am(s) | -1.9 | 2 | |
Th | Th4+ + 4 e− |
⇌ | Th(s) | -1.899 | 4 | |
Fm | Fm3+ + 3 e− |
⇌ | Fm | -1.89 | 3 | |
N | N2(g) + 2H2O(l) + 4 H+ + 2 e− | ⇌ | 2NH3OH+ | -1.87 | 2 | |
Np | Np3+ + 3 e− |
⇌ | Np(s) | -1.856 | 3 | |
Be | Be2+ + 2 e− |
⇌ | Be(s) | -1.847 | 2 | |
P | H 2PO− 2 + e− |
⇌ | P(s) + 2 OH− | -1.82 | 1 | |
U | U3+ + 3 e− |
⇌ | U(s) | -1.798 | 3 | |
Sr | Sr2+ + 2 e− |
⇌ | Sr(Hg) | -1.793 | 2 | |
B | H 2BO− 3 + H2O + 3 e− |
⇌ | B(s) + 4 OH− | -1.79 | 3 | |
Th | ThO 2 + 4 H+ + 4 e− |
⇌ | Th(s) + 2H2O | -1.789 | 4 | |
Hf | HfO2+ + 2 H+ + 4 e− |
⇌ | Hf(s) + H2O | -1.724 | 4 | |
P | HPO2− 3 + 2H2O + 3 e− |
⇌ | P(s) + 5 OH− | -1.71 | 3 | |
Si | SiO2− 3 + 3H2O + 4 e− |
⇌ | Si(s) + 6 OH− | -1.697 | 4 | |
Al | Al3+ + 3 e− |
⇌ | Al(s) | -1.662 | 3 | |
Ti | Ti2+ + 2 e− |
⇌ | Ti(s) | -1.63 | 2 | |
Zr | ZrO 2(s) + 4 H+ + 4 e− |
⇌ | Zr(s) + 2H2O | -1.553 | 4 | |
Zr | Zr4+ + 4 e− |
⇌ | Zr(s) | -1.45 | 4 | |
Ti | Ti3+ + 3 e− |
⇌ | Ti(s) | -1.37 | 3 | |
Ti | TiO(s) + 2 H+ + 2 e− | ⇌ | Ti(s) + H2O | -1.31 | 2 | |
B | B(OH)− 4 + 4H2O(l) + 8 e− |
⇌ | BH− 4 + 8 OH− |
-1.24 | 8 | |
Ga | GaO(OH)− 2 + H2O(l) + 3 e− |
⇌ | Ga(s) + 3 OH− | -1.22 | 3 | |
Ti | Ti 2O 3(s) + 2 H+ + 2 e− |
⇌ | 2TiO(s) + H2O | -1.23 | 2 | |
Zn | Zn(OH)2− 4 + 2 e− |
⇌ | Zn(s) + 4 OH− | -1.199 | 2 | |
Mn | Mn2+ + 2 e− |
⇌ | Mn(s) | -1.185 | 2 | |
Fe | Fe(CN)4− 6 + 6 H+ + 2 e− |
⇌ | Fe(s) + 6HCN(aq) | -1.16 | 2 | |
C | C(s) + 3H2O(l) + 2 e− | ⇌ | CH3OH(l) + 2 OH− | -1.148 | 2 | |
Cr | Cr(CN)3− 6 + e− |
⇌ | Cr(CN)4− 6 |
-1.143 | 1 | |
Te | Te(s) + 2 e− | ⇌ | Te2− |
-1.143 | 2 | |
V | V2+ + 2 e− |
⇌ | V(s) | -1.13 | 2 | |
Nb | Nb3+ + 3 e− |
⇌ | Nb(s) | -1.099 | 3 | |
Sn | Sn(s) + 4 H+ + 4 e− | ⇌ | SnH 4(g) |
-1.07 | 4 | |
Po | Po(s) + 2 e− | ⇌ | Po2− |
-1.021 | 2 | |
Cr | [Cr(edta)(H2O)]− + e− | ⇌ | [Cr(edta)(H2O)]2− | -0.99 | 1 | |
P | 2H3PO4(aq) + 2 H+ + 2 e− | ⇌ | (H2PO3)2(aq) + H2O(l) | -0.933 | 2 | |
C | CO2− 3 + 3 H+ + 2 e− |
⇌ | HCO− 2 + H2O(l) |
-0.93 | 2 | |
Ti | TiO2+ + 2 H+ + 4 e− |
⇌ | Ti(s) + H2O | -0.93 | 4 | |
Si | SiO 2(quartz) + 4 H+ + 4 e− |
⇌ | Si(s) + 2H2O | -0.909 | 4 | |
Cr | Cr2+ + 2 e− |
⇌ | Cr(s) | -0.9 | 2 | |
B | B(OH) 3(aq) + 3 H+ + 3 e− |
⇌ | B(s) + 3H2O | -0.89 | 3 | |
Fe | Fe(OH) 2(s) + 2 e− |
⇌ | Fe(s) + 2 OH− | -0.89 | 2 | |
Fe | Fe 2O 3(s) + 3H2O + 2 e− |
⇌ | 2Fe(OH) 2(s) + 2 OH− |
-0.86 | 2 | |
H | 2H2O + 2 e− | ⇌ | H 2(g) + 2 OH− |
-0.8277 | 2 | |
Bi | Bi(s) + 3 H+ + 3 e− | ⇌ | BiH 3 |
-0.8 | 3 | |
Zn | Zn2+ + 2 e− |
⇌ | Zn(Hg) | -0.7628 | 2 | |
Zn | Zn2+ + 2 e− |
⇌ | Zn(s) | -0.7618 | 2 | |
Ta | Ta 2O 5(s) + 10 H+ + 10 e− |
⇌ | 2Ta(s) + 5H2O | -0.75 | 10 | |
Te | 2Te(s) + 2 e− | ⇌ | Te2− 2 |
-0.74 | 2 | |
Ni | Ni(OH) 2(s) + 2 e− |
⇌ | Ni(s) + 2 OH− | -0.72 | 2 | |
Nb | Nb2O5(s) + 10 H+ + 10 e− | ⇌ | 2Nb(s) + 5H2O(l) | -0.7 | 10 | |
Ag | Ag 2S(s) + 2 e− |
⇌ | 2Ag(s) + S2− (aq) |
-0.69 | 2 | |
Te | Te2− 2 + 4 H+ + 2 e− |
⇌ | 2H2Te(g) | -0.64 | 2 | |
Sb | Sb(OH)− 4 + 3 e− |
⇌ | Sb(s) + 4 OH− | -0.639 | 3 | |
Au | [Au(CN) 2]− + e− |
⇌ | Au(s) + 2CN− |
-0.6 | 1 | |
Ta | Ta3+ + 3 e− |
⇌ | Ta(s) | -0.6 | 3 | |
Pb | PbO(s) + H2O + 2 e− | ⇌ | Pb(s) + 2 OH− | -0.580 | 2 | |
Ti | 2TiO 2(s) + 2 H+ + 2 e− |
⇌ | Ti 2O 3(s) + H2O |
-0.56 | 2 | |
Ga | Ga3+ + 3 e− |
⇌ | Ga(s) | -0.549 | 3 | |
U | U4+ + e− |
⇌ | U3+ |
-0.52 | 1 | |
P | H 3PO 2(aq) + H+ + e− |
⇌ | P(white)[note 1] + 2H2O | -0.508 | 1 | |
P | H 3PO 3(aq) + 2 H+ + 2 e− |
⇌ | H 3PO 2(aq) + H2O |
-0.499 | 2 | |
Ni | NiO 2(s) + 2H2O + 2 e− |
⇌ | Ni(OH) 2(s) + 2 OH− |
-0.49 | 2 | |
Sb | Sb(OH)− 6 + 2 e− |
⇌ | Sb(OH)− 4 + 2 OH− |
-0.465 | 2 | |
P | H 3PO 3(aq) + 3 H+ + 3 e− |
⇌ | P(red)[note 1] + 3H2O | -0.454 | 3 | |
Bi | Bi2O3(s) + 3H2O(l) + 6 e− | ⇌ | Bi(s) + 6 OH− | -0.452 | 6 | |
Ta | TaF2− 7 + 7 H+ + 5 e− |
⇌ | Ta(s) + 7HF(l) | -0.45 | 5 | |
In | In3+ + 2 e− |
⇌ | In+ | -0.444 | 2 | |
Cu | Cu(CN)− 2 + e− |
⇌ | Cu(s) + 2CN− |
-0.44 | 1 | |
Fe | Fe2+ + 2 e− |
⇌ | Fe(s) | -0.44 | 2 | |
C | 2CO 2(g) + 2 H+ + 2 e− |
⇌ | HOOCCOOH(aq) | -0.43 | 2 | |
Cr | Cr3+ + e− |
⇌ | Cr2+ |
-0.407 | 1 | |
Cd | Cd2+ + 2 e− |
⇌ | Cd(s) | -0.4 | 2 | |
Ti | Ti3+ + e− |
⇌ | Ti2+ |
-0.37 | 1 | |
Cu | Cu 2O(s) + H2O + 2 e− |
⇌ | 2Cu(s) + 2 OH− | -0.36 | 2 | |
Pb | PbSO 4(s) + 2 e− |
⇌ | Pb(s) + SO2− 4 |
-0.3588 | 2 | |
Pb | PbSO 4(s) + 2 e− |
⇌ | Pb(Hg) + SO2− 4 |
-0.3505 | 2 | |
Eu | Eu3+ + e− |
⇌ | Eu2+ |
-0.35 | 1 | |
In | In3+ + 3 e− |
⇌ | In(s) | -0.34 | 3 | |
Tl | Tl+ + e− |
⇌ | Tl(s) | -0.34 | 1 | |
Ge | Ge(s) + 4 H+ + 4 e− | ⇌ | GeH 4(g) |
-0.29 | 4 | |
Co | Co2+ + 2 e− |
⇌ | Co(s) | -0.28 | 2 | |
P | H 3PO 4(aq) + 2 H+ + 2 e− |
⇌ | H 3PO 3(aq) + H2O |
-0.276 | 2 | |
N | N2(g) + 8 H+ + 6 e− | ⇌ | 2NH+ 4 |
-0.27 | 6 | |
V | V3+ + e− |
⇌ | V2+ |
-0.26 | 1 | |
Ni | Ni2+ + 2 e− |
⇌ | Ni(s) | -0.257 | 2 | |
S | 2HSO− 4 + 2 H+ + 2 e− |
⇌ | S2O2− 6 + 2H2O(l) |
-0.253 | 2 | |
As | As(s) + 3 H+ + 3 e− | ⇌ | AsH 3(g) |
-0.23 | 3 | |
N | N2(g) + 5 H+ + 4 e− | ⇌ | N2H+ 5 |
-0.23 | 4 | |
Ga | Ga+ + e− |
⇌ | Ga(s) | -0.2 | 1 | |
Ag | AgI(s) + e− | ⇌ | Ag(s) + I− |
-0.15224 | 1 | |
Ge | GeO2(s) + 4 H+ + 4 e− | ⇌ | Ge(s) + 2H2O(l) | -0.15 | 4 | |
Mo | MoO 2(s) + 4 H+ + 4 e− |
⇌ | Mo(s) + 2H2O | -0.15 | 4 | |
Si | Si(s) + 4 H+ + 4 e− | ⇌ | SiH 4(g) |
-0.14 | 4 | |
Sn | Sn2+ + 2 e− |
⇌ | Sn(s) | -0.13 | 2 | |
O | O 2(g) + H+ + e− |
⇌ | HO• 2(aq) |
-0.13 | 1 | |
In | In+ + e− | ⇌ | In(s) | -0.126 | 1 | |
Pb | Pb2+ + 2 e− |
⇌ | Pb(s) | -0.126 | 2 | |
W | WO 2(s) + 4 H+ + 4 e− |
⇌ | W(s) + 2H2O | -0.12 | 4 | |
Ge | GeO 2(s) + 2 H+ + 2 e− |
⇌ | GeO(s) + H2O | -0.118 | 2 | |
P | P(red) + 3 H+ + 3 e− | ⇌ | PH 3(g) |
-0.111 | 3 | |
C | CO 2(g) + 2 H+ + 2 e− |
⇌ | HCOOH(aq) | -0.11 | 2 | |
Se | Se(s) + 2 H+ + 2 e− | ⇌ | H 2Se(g) |
-0.11 | 2 | |
C | CO 2(g) + 2 H+ + 2 e− |
⇌ | CO(g) + H2O | -0.11 | 2 | |
Sn | α-SnO(s) + 2 H+ + 2 e− | ⇌ | Sn(s) + H2O | -0.104 | 2 | |
Cu | Cu(NH 3)+ 2 + e− |
⇌ | Cu(s) + 2NH 3(aq) |
-0.1 | 1 | |
Nb | Nb2O5(s) + 10 H+ + 4 e− | ⇌ | 2Nb3+ + 5H2O(l) |
-0.1 | 4 | |
W | WO 3(aq) + 6 H+ + 6 e− |
⇌ | W(s) + 3H2O | -0.09 | 6 | |
Sn | SnO 2(s) + 2 H+ + 2 e− |
⇌ | α-SnO(s) + H2O | -0.088 | 2 | |
Fe | Fe 3O 4(s) + 8 H+ + 8 e− |
⇌ | 3Fe(s) + 4H2O | -0.085 | 8 | |
V | VOH2+ + H+ + e− |
⇌ | V2+ + H2O(l) |
-0.082 | 1 | |
P | P(white) + 3 H+ + 3 e− | ⇌ | PH 3(g) |
-0.063 | 3 | |
N | N2O(g) + H2O(l) + 6 H+ + 4 e− | ⇌ | 2NH3OH+ | -0.05 | 4 | |
Fe | Fe3+ + 3 e− |
⇌ | Fe(s) | -0.04 | 3 | |
C | HCOOH(aq) + 2 H+ + 2 e− | ⇌ | HCHO(aq) + H2O | -0.034 | 2 | |
H | 2 H+ + 2 e− | ⇌ | H 2(g) |
0 | 2 | |
Ag | AgBr(s) + e− | ⇌ | Ag(s) + Br− |
0.07133 | 1 | |
S | S 4O2− 6 + 2 e− |
⇌ | 2S 2O2− 3 |
0.08 | 2 | |
N | N 2(g) + 2H2O + 6 H+ + 6 e− |
⇌ | 2NH 4OH(aq) |
0.092 | 6 | |
Hg | HgO(s) + H2O + 2 e− | ⇌ | Hg(l) + 2 OH− | 0.0977 | 2 | |
Cu | Cu(NH 3)2+ 4 + e− |
⇌ | Cu(NH 3)+ 2 + 2NH 3(aq) |
0.1 | 1 | |
Ru | Ru(NH 3)3+ 6 + e− |
⇌ | Ru(NH 3)2+ 6 |
0.1 | 1 | |
N | N 2H 4(aq) + 4H2O + 2 e− |
⇌ | 2NH+ 4 + 4 OH− |
0.11 | 2 | |
Mo | H 2MoO 4(aq) + 6 H+ + 6 e− |
⇌ | Mo(s) + 4H2O | 0.11 | 6 | |
Ge | Ge4+ + 4 e− |
⇌ | Ge(s) | 0.12 | 4 | |
C | C(s) + 4 H+ + 4 e− | ⇌ | CH 4(g) |
0.13 | 4 | |
C | HCHO(aq) + 2 H+ + 2 e− | ⇌ | CH 3OH(aq) |
0.13 | 2 | |
S | S(s) + 2 H+ + 2 e− | ⇌ | H 2S(g) |
0.144 | 2 | |
Sb | Sb2O3(s) + 6 H+ + 6 e− | ⇌ | 2Sb(s) + 3H2O | 0.15 | 6 | [6]: 789 |
Sn | Sn4+ + 2 e− |
⇌ | Sn2+ |
0.151 | 2 | |
S | HSO− 4 + 3 H+ + 2 e− |
⇌ | SO 2(aq) + 2H2O |
0.158 | 2 | |
Cu | Cu2+ + e− |
⇌ | Cu+ |
0.159 | 1 | |
U | UO2+ 2 + e− |
⇌ | UO+ 2 |
0.163 | 1 | |
S | SO2− 4 + 4 H+ + 2 e− |
⇌ | SO 2(aq) + 2H2O |
0.17 | 2 | |
Ti | TiO2+ + 2 H+ + e− |
⇌ | Ti3+ + H2O |
0.19 | 1 | |
Sb | SbO+ + 2 H+ + 3 e− |
⇌ | Sb(s) + H2O | 0.2 | 3 | |
Fe | 3Fe 2O 3(s) + 2 H+ + 2 e− |
⇌ | 2Fe 3O 4(s) + H2O |
0.22 | 2 | |
Ag | AgCl(s) + e− | ⇌ | Ag(s) + Cl− |
0.22233 | 1 | |
As | H 3AsO 3(aq) + 3 H+ + 3 e− |
⇌ | As(s) + 3H2O | 0.24 | 3 | |
Ru | Ru3+ (aq) + e− |
⇌ | Ru2+ (aq) |
0.249 | 1 | |
Pb | PbO2(s) + H2O + 2 e− | ⇌ | α-PbO(s) + 2 OH− | 0.254 | 2 | |
Ge | GeO(s) + 2 H+ + 2 e− | ⇌ | Ge(s) + H2O | 0.26 | 2 | |
Hg | Hg2Cl2(s) + 2 e− | ⇌ | 2Hg(l) + 2Cl− | 0.27 | 2 | |
U | UO+ 2 + 4 H+ + e− |
⇌ | U4+ + 2H2O |
0.273 | 1 | |
Re | Re3+ + 3 e− |
⇌ | Re(s) | 0.300 | 3 | |
At | At + e− | ⇌ | At− | 0.3 | 1 | |
Bi | Bi3+ + 3 e− |
⇌ | Bi(s) | 0.308 | 3 | |
C | 2HCNO + 2 H+ + 2 e− | ⇌ | (CN)2 + 2H2O | 0.330 | 2 | |
Cu | Cu2+ + 2 e− |
⇌ | Cu(s) | 0.337 | 2 | |
V | VO2+ + 2 H+ + e− |
⇌ | V3+ + H2O |
0.337 | 1 | |
Sb | Sb2O4(s) + 2 H+ + 2 e− | ⇌ | Sb2O3(s) + H2O(l) | 0.342 | 2 | |
At | At+ + 2 e− | ⇌ | At- | 0.36 | 2 | |
Fe | [Fe(CN) 6]3− + e− |
⇌ | [Fe(CN) 6]4− |
0.3704 | 1 | |
C | (CN)2 + 2 H+ + 2 e− | ⇌ | 2HCN | 0.373 | 2 | |
P | (H2PO3)2(aq) + 2 H+ + 2 e− | ⇌ | 2H3PO3 | 0.38 | 2 | |
S | 2SO2(aq) + 2 H+ + 2 e− | ⇌ | S2O2− 3 + H2O(l) |
0.4 | 2 | |
O | O 2(g) + 2H2O + 4 e− |
⇌ | 4 OH−(aq) | 0.401 | 4 | |
Mo | H 2MoO 4 + 6 H+ + 3 e− |
⇌ | Mo3+ + 4H2O |
0.43 | 3 | |
Ru | Ru2+ (aq) + 2 e− |
⇌ | Ru | 0.455 | 2 | |
V | VO(OH)+ + 2 H+ + e− | ⇌ | VOH2+ + H2O(l) |
0.481 | 1 | |
C | CH 3OH(aq) + 2 H+ + 2 e− |
⇌ | CH 4(g) + H2O |
0.5 | 2 | |
S | SO 2(aq) + 4 H+ + 4 e− |
⇌ | S(s) + 2H2O | 0.5 | 4 | |
S | 4SO 2(aq) + 4 H+ + 8 e− |
⇌ | S4O2− 6 + 2H2O(l) |
0.51 | 8 | |
Cu | Cu+ + e− |
⇌ | Cu(s) | 0.52 | 1 | |
C | CO(g) + 2 H+ + 2 e− | ⇌ | C(s) + H2O | 0.52 | 2 | |
I | I− 3 + 2 e− |
⇌ | 3I− |
0.53 | 2 | |
Te | TeO2(s) + 4 H+ + 4 e− | ⇌ | Te(s) + 2H2O(l) | 0.53 | 4 | |
Cu | Cu2+ + Cl− + e− |
⇌ | CuCl(s) | 0.54 | 1 | |
I | I 2(s) + 2 e− |
⇌ | 2I− |
0.54 | 2 | |
Au | [AuI 4]− + 3 e− |
⇌ | Au(s) + 4I− |
0.56 | 3 | |
As | H 3AsO 4(aq) + 2 H+ + 2 e− |
⇌ | H 3AsO 3(aq) + H2O |
0.56 | 2 | |
S | S2O2− 6 + 4 H+ + 2 e− |
⇌ | 2H2SO3 | 0.569 | 2 | |
Au | [AuI 2]− + e− |
⇌ | Au(s) + 2I− |
0.58 | 1 | |
Mn | MnO− 4 + 2H2O + 3 e− |
⇌ | MnO 2(s) + 4 OH− |
0.595 | 3 | |
S | S 2O2− 3 + 6 H+ + 4 e− |
⇌ | 2S(s) + 3H2O | 0.6 | 4 | |
Fe | Fc+ + e− |
⇌ | Fc(s) | 0.63 | 1 | |
Mo | H 2MoO 4(aq) + 2 H+ + 2 e− |
⇌ | MoO 2(s) + 2H2O |
0.65 | 2 | |
N | HN3(aq) + 11 H+ + 8 e− | ⇌ | 3NH+ 4 |
0.69 | 8 | |
O | O 2(g) + 2 H+ + 2 e− |
⇌ | H 2O 2(aq) |
0.695 | 2 | |
Sb | Sb2O5(s) + 4 H+ + 4 e− | ⇌ | Sb2O3(s) + 2H2O | 0.699 | 4 | |
C | + 2 H+ + 2 e− | ⇌ | 0.6992 | 2 | ||
V | H2V10O4− 28 + 24 H+ + 10 e− |
⇌ | 10VO(OH)+ + 8H2O(l) | 0.723 | 10 | |
Pt | PtCl2− 6 + 2 e− |
⇌ | PtCl2− 4 + 2Cl− |
0.726 | 2 | |
Fe | Fe 2O 3(s) + 6 H+ + 2 e− |
⇌ | 2Fe2+ + 3H2O |
0.728 | 2 | |
Se | H 2SeO 3(aq) + 4 H+ + 4 e− |
⇌ | Se(s) + 3H2O | 0.74 | 4 | |
At | AtO+ + 2 H+ + 2 e− | ⇌ | At+ + H2O | 0.74 | 2 | |
Tl | Tl3+ + 3 e− |
⇌ | Tl(s) | 0.741 | 3 | |
No | No3+ + e− |
⇌ | No2+ |
0.75 | 1 | |
Pt | PtCl2− 4 + 2 e− |
⇌ | Pt(s) + 4Cl− |
0.758 | 2 | |
Br | BrO− + H2O(l) + 2 e− | ⇌ | Br− + 2 OH− | 0.76 | 2 | |
Po | Po4+ + 4 e− | ⇌ | Po | 0.76 | 4 | |
S | (SCN)2 + 2 e− | ⇌ | 2SCN- | 0.769 | 2 | |
Fe | Fe3+ + e− |
⇌ | Fe2+ |
0.771 | 1 | |
Hg | Hg2+ 2 + 2 e− |
⇌ | 2Hg(l) | 0.7973 | 2 | |
Ag | Ag+ + e− |
⇌ | Ag(s) | 0.7996 | 1 | |
N | 2NO− 3(aq) + 4 H+ + 2 e− |
⇌ | N 2O 4(g) + 2H2O |
0.803 | 2 | |
Fe | 2FeO2− 4 + 5H2O + 6 e− |
⇌ | Fe 2O 3(s) + 10 OH− |
0.81 | 6 | |
Au | [AuBr 4]− + 3 e− |
⇌ | Au(s) + 4Br− |
0.85 | 3 | |
Hg | Hg2+ + 2 e− |
⇌ | Hg(l) | 0.85 | 2 | |
Ir | [IrCl 6]2− + e− |
⇌ | [IrCl 6]3− |
0.87 | 1 | |
Mn | MnO− 4 + H+ + e− |
⇌ | HMnO− 4 |
0.9 | 1 | |
Po | Po4+ + 2 e− | ⇌ | Po2+ | 0.9 | 2 | |
Hg | 2Hg2+ + 2 e− |
⇌ | Hg2+ 2 |
0.91 | 2 | |
Pd | Pd2+ + 2 e− |
⇌ | Pd(s) | 0.915 | 2 | |
Au | [AuCl 4]− + 3 e− |
⇌ | Au(s) + 4Cl− |
0.93 | 3 | |
N | NO− 3 + 3 H+ + 2 e− |
⇌ | HNO2(aq) | 0.94 | 2 | |
Mn | MnO 2(s) + 4 H+ + e− |
⇌ | Mn3+ + 2H2O |
0.95 | 1 | |
N | NO− 3(aq) + 4 H+ + 3 e− |
⇌ | NO(g) + 2H2O(l) | 0.958 | 3 | |
Au | [AuBr 2]− + e− |
⇌ | Au(s) + 2Br− |
0.96 | 1 | |
Fe | Fe 3O 4(s) + 8 H+ + 2 e− |
⇌ | 3Fe2+ + 4H2O |
0.98 | 2 | |
Xe | [HXeO 6]3− + 2H2O + 2 e− |
⇌ | [HXeO 4]− + 4 OH− |
0.99 | 2 | |
N | HNO2(aq) + H+ + e− | ⇌ | NO(g) + H2O(l) | 0.996 | 1 | |
At | HAtO + H+ + e− | ⇌ | At + H2O | 1.0 | 1 | |
V | [VO 2]+ (aq) + 2 H+ + e− |
⇌ | [VO]2+ (aq) + H2O |
1 | 1 | |
Te | H 6TeO 6(aq) + 2 H+ + 2 e− |
⇌ | TeO 2(s) + 4H2O |
1.02 | 2 | |
N | NO2(g) + 2 H+ + 2 e− | ⇌ | NO(g) + H2O(l) | 1.03 | 2 | |
Br | Br− 3 + 2 e− |
⇌ | 3Br− |
1.05 | 2 | |
Sb | Sb2O5(s) + 2 H+ + 2 e− | ⇌ | Sb2O4(s) + H2O(l) | 1.055 | 2 | |
I | ICl− 2 + e− |
⇌ | 2Cl− + I(s) |
1.06 | 1 | |
Br | Br 2(l) + 2 e− |
⇌ | 2Br− |
1.066 | 2 | |
N | N2O4(g) + 2 H+ + 2 e− | ⇌ | 2HNO2 | 1.07 | 2 | |
Br | Br 2(aq) + 2 e− |
⇌ | 2Br− |
1.0873 | 2 | |
Ru | RuO 2 + 4 H+ + 2 e− |
⇌ | Ru2+ (aq) + 2H2O |
1.120 | 2 | |
Cu | Cu2+ + 2CN− + e− |
⇌ | Cu(CN)− 2 |
1.12 | 1 | |
I | IO− 3 + 5 H+ + 4 e− |
⇌ | HIO(aq) + 2H2O | 1.13 | 4 | |
O | H2O2(aq) + H+ + e− | ⇌ | H2O(l) + HO• | 1.14 | 1 | |
Au | [AuCl 2]− + e− |
⇌ | Au(s) + 2Cl− |
1.15 | 1 | |
Se | HSeO− 4 + 3 H+ + 2 e− |
⇌ | H 2SeO 3(aq) + H2O |
1.15 | 2 | |
Ag | Ag 2O(s) + 2 H+ + 2 e− |
⇌ | 2Ag(s) + H2O | 1.17 | 2 | |
Cl | ClO− 3 + 2 H+ + e− |
⇌ | ClO 2(g) + H2O |
1.175 | 1 | |
Xe | [HXeO 6]3− + 5H2O + 8 e− |
⇌ | Xe(g) + 11 OH− | 1.18 | 8 | |
Pt | Pt2+ + 2 e− |
⇌ | Pt(s) | 1.188 | 2 | |
Cl | ClO 2(g) + H+ + e− |
⇌ | HClO 2(aq) |
1.19 | 1 | |
I | 2IO− 3 + 12 H+ + 10 e− |
⇌ | I 2(s) + 6H2O |
1.2 | 10 | |
Mn | MnO 2(s) + 4 H+ + 2 e− |
⇌ | Mn2+ + 2H2O |
1.224 | 2 | |
O | O 2(g) + 4 H+ + 4 e− |
⇌ | 2H2O | 1.229 | 4 | |
N | N2H+ 5 + 3 H+ + 2 e− |
⇌ | 2NH+ 4 |
1.28 | 2 | |
Cl | ClO− 4 + 2 H+ + 2 e− |
⇌ | ClO− 3 + H2O |
1.23 | 2 | |
Ru | [Ru(bipy) 3]3+ + e− |
⇌ | [Ru(bipy) 3]2+ |
1.24 | 1 | |
Xe | [HXeO 4]− + 3H2O + 6 e− |
⇌ | Xe(g) + 7 OH− | 1.24 | 6 | |
N | 2NO− 3 + 12 H+ + 10 e− |
⇌ | N2(g) + 6H2O(l) | 1.25 | 10 | |
Tl | Tl3+ + 2 e− |
⇌ | Tl+ |
1.25 | 2 | |
N | 2HNO2(aq) + 4 H+ + 4 e− | ⇌ | N2O(g) + 3H2O(l) | 1.297 | 4 | |
Cr | Cr 2O2− 7 + 14 H+ + 6 e− |
⇌ | 2Cr3+ + 7H2O |
1.38 | 6 | |
N | NH3OH+ + 2 H+ + 2 e− | ⇌ | NH+ 4 + H2O(l) |
1.35 | 2 | |
Cl | Cl 2(g) + 2 e− |
⇌ | 2Cl− |
1.36 | 2 | |
Ru | RuO− 4(aq) + 8 H+ + 5 e− |
⇌ | Ru2+ (aq) + 4H2O |
1.368 | 5 | |
Ru | RuO 4 + 4 H+ + 4 e− |
⇌ | RuO 2 + 2H2O |
1.387 | 4 | |
Co | CoO 2(s) + 4 H+ + e− |
⇌ | Co3+ + 2H2O |
1.42 | 1 | |
N | 2NH 3OH+ + H+ + 2 e− |
⇌ | N 2H+ 5 + 2H2O |
1.42 | 2 | |
I | 2HIO(aq) + 2 H+ + 2 e− | ⇌ | I 2(s) + 2H2O |
1.44 | 2 | |
Br | BrO− 3 + 5 H+ + 4 e− |
⇌ | HBrO(aq) + 2H2O | 1.447 | 4 | |
Pb | β-PbO 2(s) + 4 H+ + 2 e− |
⇌ | Pb2+ + 2H2O |
1.46 | 2 | |
Pb | α-PbO 2(s) + 4 H+ + 2 e− |
⇌ | Pb2+ + 2H2O |
1.468 | 2 | |
Br | 2BrO− 3 + 12 H+ + 10 e− |
⇌ | Br 2(l) + 6H2O |
1.48 | 10 | |
At | HAtO3 + 4 H+ + 4 e− | ⇌ | HAtO + 2H2O | 1.5 | 4 | |
Mn | MnO− 4 + 8 H+ + 5 e− |
⇌ | Mn2+ + 4H2O |
1.51 | 5 | |
O | HO• 2 + H+ + e− |
⇌ | H 2O 2(aq) |
1.51 | 1 | |
Au | Au3+ + 3 e− |
⇌ | Au(s) | 1.52 | 3 | |
Ru | RuO2− 4(aq) + 8 H+ + 4 e− |
⇌ | Ru2+ (aq) + 4H2O |
1.563 | 4 | |
N | 2NO(g) + 2 H+ + 2 e− | ⇌ | N2O(g) + H2O(l) | 1.59 | 2 | |
Ni | NiO 2(s) + 2 H+ + 2 e− |
⇌ | Ni2+ + 2 OH− |
1.59 | 2 | |
Ce | Ce4+ + e− |
⇌ | Ce3+ |
1.61 | 1 | |
Cl | 2HClO(aq) + 2 H+ + 2 e− | ⇌ | Cl 2(g) + 2H2O |
1.63 | 2 | |
I | IO− 4 + 2 H+ + 2 e− |
⇌ | IO− 3 + H2O |
1.64 | 2 | |
Ag | Ag 2O 3(s) + 6 H+ + 4 e− |
⇌ | 2Ag+ + 3H2O |
1.67 | 4 | |
Cl | HClO 2(aq) + 2 H+ + 2 e− |
⇌ | HClO(aq) + H2O | 1.67 | 2 | |
Pb | Pb4+ + 2 e− |
⇌ | Pb2+ |
1.69 | 2 | |
Mn | MnO− 4 + 4 H+ + 3 e− |
⇌ | MnO 2(s) + 2H2O |
1.7 | 3 | |
Br | BrO− 4 + 2 H+ + 2 e− |
⇌ | BrO− 3 + H2O |
1.74 | 2 | |
Ag | AgO(s) + 2 H+ + e− | ⇌ | Ag+ + H2O |
1.77 | 1 | |
N | N2O(g) + 2 H+ + 2 e− | ⇌ | N2(g) + H2O(l) | 1.77 | 2 | [6]: 789 |
O | H 2O 2(aq) + 2 H+ + 2 e− |
⇌ | 2H2O | 1.78 | 2 | |
Au | Au+ + e− |
⇌ | Au(s) | 1.83 | 1 | |
Co | Co3+ + e− |
⇌ | Co2+ |
1.92 | 1 | |
Ag | Ag2+ + e− |
⇌ | Ag+ |
1.98 | 1 | |
O | S 2O2− 8 + 2 e− |
⇌ | 2SO2− 4 |
2.01 | 2 | |
O | O 3(g) + 2 H+ + 2 e− |
⇌ | O 2(g) + H2O |
2.075 | 2 | |
Mn | HMnO− 4 + 3 H+ + 2 e− |
⇌ | MnO 2(s) + 2H2O |
2.09 | 2 | |
Xe | XeO 3(aq) + 6 H+ + 6 e− |
⇌ | Xe(g) + 3H2O | 2.12 | 6 | |
Xe | H 4XeO 6(aq) + 8 H+ + 8 e− |
⇌ | Xe(g) + 6H2O | 2.18 | 8 | |
Fe | FeO2− 4 + 8 H+ + 3 e− |
⇌ | Fe3+ + 4H2O |
2.2 | 3 | |
Xe | XeF 2(aq) + 2 H+ + 2 e− |
⇌ | Xe(g) + 2HF(aq) | 2.32 | 2 | |
O | HO• + H+ + e− | ⇌ | H2O(l) | 2.38 | 1 | |
Xe | H 4XeO 6(aq) + 2 H+ + 2 e− |
⇌ | XeO 3(aq) + 3H2O |
2.42 | 2 | |
F | F 2(g) + 2 e− |
⇌ | 2F− |
2.87 | 2 | |
Cm | Cm4+ + e– | ⇌ | Cm3+ | 3.0 | 1 | |
F | F 2(g) + 2 H+ + 2 e− |
⇌ | 2HF(aq) | 3.077 | 2 | |
Tb | Tb4+ + e– | ⇌ | Tb3+ | 3.1 | 1 | |
Pr | Pr4+ + e– | ⇌ | Pr3+ | 3.2 | 1 | |
Kr | KrF 2(aq) + 2 e− |
⇌ | Kr(g) + 2F− (aq) |
3.27 | 2 |
See also
[edit]- Galvanic series lists electrode potentials in saltwater
- Standard apparent reduction potentials in biochemistry at pH 7
- Reactivity series#Comparison with standard electrode potentials
Notes
[edit]References
[edit]- ^ a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae af ag ah ai aj ak al am an ao ap aq ar as at au av aw ax ay az ba bb bc bd be bf bg bh bi bj bk bl bm bn bo bp bq br bs bt bu bv Lide, David R., ed. (2006). CRC Handbook of Chemistry and Physics (87th ed.). Boca Raton, FL: CRC Press. ISBN 0-8493-0487-3.
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- ^ Courtney, Arlene. "Oxidation Reduction Chemistry of the Elements". Ch 412 Advanced Inorganic Chemistry: Reading Materials. Western Oregon University.
- ^ Leszczyński, P.J.; Grochala, W. (2013). "Strong Cationic Oxidizers: Thermal Decomposition, Electronic Structure and Magnetism of Their Compounds" (PDF). Acta Chim. Slov. 60 (3): 455–470. PMID 24169699. Archived (PDF) from the original on 2022-10-09.
External links
[edit]- Chemistry LibreTexts (2021-04-26). "P1: Standard Reduction Potentials by Element". Chemistry LibreTexts. Retrieved 2021-11-30.
- California State University, Northridge (CSUN). "Standard Reduction Potentials" (PDF). csun.edu. Archived (PDF) from the original on 2017-12-15. Retrieved 2021-11-30.
- Wardman, Peter (1989). "Reduction potentials of one-electron couples involving free radicals in aqueous solution" (PDF). srd.nist.gov. Archived (PDF) from the original on 2022-10-09. Retrieved 2021-11-30.
- http://www.jesuitnola.org/upload/clark/Refs/red_pot.htm Archived 2008-07-20 at the Wayback Machine
- https://web.archive.org/web/20150924015049/http://www.fptl.ru/biblioteka/spravo4niki/handbook-of-Chemistry-and-Physics.pdf
- http://hyperphysics.phy-astr.gsu.edu/Hbase/tables/electpot.html#c1