Iridium(V) fluoride

Iridium(V) fluoride
Names
	Other names Iridium pentafluoride
Identifiers
CAS Number	14568-19-5 ;
3D model (JSmol)	monomer: Interactive image; tetramer: Interactive image;
	InChI InChI=1S/5FH.Ir/h5*1H;/q;;;;;+5/p-5 Key: AVEYGPFFIPYHQT-UHFFFAOYSA-I;
	SMILES monomer: F[Ir](F)(F)(F)F; tetramer: F[Ir-]1(F)(F)(F)[F+][Ir-](F)(F)(F)(F)[F+][Ir-](F)(F)(F)(F)[F+][Ir-](F)(F)(F)(F)[F+]1;
Properties
Chemical formula	IrF5
Molar mass	287.209 g/mol
Appearance	yellow solid
Melting point	104.5 °C (220.1 °F; 377.6 K)
Related compounds
Other cations	Rhodium(V) fluoride, Osmium pentafluoride, Platinum(V) fluoride
Related compounds	Iridium(IV) fluoride, Iridium hexafluoride
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Iridium(V) fluoride, IrF₅, is a chemical compound of iridium and fluorine. A highly reactive yellow low melting solid, it has a tetrameric structure, Ir₄F₂₀, which contains octahedrally coordinated iridium atoms.^[1] This structure is shared with RuF₅ and OsF₅. It can be prepared by the controlled decomposition of IrF₆^[1] or the reduction of IrF₆ with silicon powder or H₂ in anhydrous HF.^[2]^[3]

${\ce {2IrF6 + H2 -> 2IrF5 + 2HF}}$
${\ce {4IrF6 + Si -> 4IrF5 + SiF4}}$

References

^ ^a ^b Egon Wiberg, Arnold Frederick Holleman (2001) Inorganic Chemistry, Elsevier ISBN 0-12-352651-5
^ Paine, Robert T.; Asprey, Larned B. (1975). "Reductive syntheses of transition metal fluoride compounds. Synthesis of rhenium, osmium, and iridium pentafluorides and tetrafluorides". Inorganic Chemistry. 14 (5): 1111–1113. doi:10.1021/ic50147a030.
^ Bartlett, Neil; Rao, P. R. (1965). "Iridium pentafluoride". Chem. Commun. (12): 252–253. doi:10.1039/C19650000252.

[Wiberg&Holleman-1] Egon Wiberg, Arnold Frederick Holleman (2001) Inorganic Chemistry, Elsevier ISBN 0-12-352651-5

[2] Paine, Robert T.; Asprey, Larned B. (1975). "Reductive syntheses of transition metal fluoride compounds. Synthesis of rhenium, osmium, and iridium pentafluorides and tetrafluorides". Inorganic Chemistry. 14 (5): 1111–1113. doi:10.1021/ic50147a030.

[3] Bartlett, Neil; Rao, P. R. (1965). "Iridium pentafluoride". Chem. Commun. (12): 252–253. doi:10.1039/C19650000252.

[1]

[2]

[3]

See also

References