Potassium hexafluoroantimonate
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| Names | |
|---|---|
| IUPAC name
potassium;hexafluoroantimony(1-)
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.156.339 |
| EC Number |
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| F6KSb | |
| Molar mass | 274.849 g·mol−1 |
| Appearance | powder |
| Melting point | 846 |
| Boiling point | 1505 |
| Hazards | |
| GHS labelling:[1] | |
 
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| Warning | |
| H302, H332, H411 | |
| P261, P264, P270, P271, P273, P301+P317, P304+P340, P317, P330, P391, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Potassium hexafluoroantimonate is an inorganic chemical compound with the chemical formula KSbF6.[2]
Synthesis
[edit]Potassium hexafluoroantimonate can be prepared by reacting potassium pyroantimonate K2H2Sb2O7 with hydrogen fluoride or by treating the product of the reaction of a mixture of solid antimony(III) oxide and potassium hydroxide with hydrogen peroxide solution (30%) with hydrochloric acid (48%).[3]
Also, the compound can be prepared by reacting antimony pentafluoride and potassium hexafluoromanganate.[4]
- SbF5 + K2MnF6 → 4KSbF6 + 2MnF3 + F2
Uses
[edit]Potassium hexafluoroantimonate is used as a pharmaceutical intermediate.[5]
Chemical properties
[edit]Potassium hexafluoroaluminate can cause violent reactions with strong acids and oxidizing agents.[6]
References
[edit]- ^ "Potassium hexafluoroantimonate". pubchem.ncbi.nlm.nih.gov.
- ^ McCarthy, J. (6 December 2012). The Rare Earths in Modern Science and Technology: Volume 3. Springer Science & Business Media. p. 105. ISBN 978-1-4613-3406-4.
- ^ Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 3217. ISBN 978-0-412-30120-9. Retrieved 15 June 2024.
- ^ Ebnesajjad, Sina (11 May 2013). Introduction to Fluoropolymers: Materials, Technology and Applications. William Andrew. p. 10. ISBN 978-1-4557-7551-4. Retrieved 15 June 2024.
- ^ "Potassium hexafluoroantimonate(V) | CAS 16893-92-8 | SCBT - Santa Cruz Biotechnology". Santa Cruz Biotechnology. Retrieved 15 June 2024.
- ^ "Potassium hexafluoroantimonate(V)". Sigma Aldrich. Retrieved 15 June 2024.