Caesium enneabromodibismuthate

Caesium enneabromodibismuthate
Identifiers
CAS Number	2270200-10-5 ;
Properties
Chemical formula	Bi2Br9Cs3
Molar mass	1535.813 g·mol−1
Appearance	Yellow crystals
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Caesium enneabromodibismuthate is an inorganic compound with the formula Cs₃Bi₂Br₉. It is one of the coordination complexes formed by caesium, bismuth and bromine.^[1] At room temperature, it is trigonal (P3m1) and it undergoes phase transformation to monoclinic phase (C12/c1) when the temperature is below 96 K.^[2]

Preparation

Traditionally, it can be synthesized from a hydrobromic acid solution of stoichiometric amounts of caesium bromide and bismuth hydroxide or bismuth(III) oxide,^[3] crystals are formed by cooling the hot, saturated solution.^[4] It can also be obtained by reacting caesium bromide and bismuth(III) bromide in DMF, followed by vaporizing the solvent.^[5] Its nanocrystals can be synthesized in 1-octadecene at 170 °C using caesium oleate and bismuth(III) bromide as precursors.^[6]

References

^ Tran, Minh N.; Cleveland, Iver J.; Aydil, Eray S. (January 2021). "Physical vapor deposition of the halide perovskite CsBi₂Br₇". Journal of Vacuum Science & Technology A. 39 (1): 013409. Bibcode:2021JVSTA..39a3409T. doi:10.1116/6.0000604. eISSN 1520-8559. ISSN 0734-2101. S2CID 234115452.
^ Tran, Minh N.; Cleveland, Iver J.; Aydil, Eray S. (2020). "Resolving the discrepancies in the reported optical absorption of low-dimensional non-toxic perovskites, Cs₃Bi₂Br₉ and Cs₃BiBr₆". Journal of Materials Chemistry C. 8 (30): 10456–10463. doi:10.1039/d0tc02783a. eISSN 2050-7534. ISSN 2050-7526. S2CID 225578432.
^ Terao, Hiromitsu; Ishihara, Hideta; Okuda, Tsutomu; Yamada, Koji; Weiss, Alarich (1 December 1992). "Phase Transition in Cesium Enneabromodibismuthate(III), Cs₃Bi₂Br₉; an ⁸¹Br and ²⁰⁹Bi NQR Study". Zeitschrift für Naturforschung A. 47 (12): 1259–1261. doi:10.1515/zna-1992-1217. eISSN 1865-7109. ISSN 0932-0784. S2CID 197265206.
^ Timmermans, C. W. M.; Blasse, G. (1 August 1981). "On the Luminescence of Cs₃Bi₂Br₉ Single Crystals". Physica Status Solidi B (in German). 106 (2): 647–655. Bibcode:1981PSSBR.106..647T. doi:10.1002/pssb.2221060230. eISSN 1521-3951. ISSN 0370-1972.
^ Romani, Lidia; Speltini, Andrea; Dibenedetto, Carlo Nazareno; Listorti, Andrea; Ambrosio, Francesco; Mosconi, Edoardo; Simbula, Angelica; Saba, Michele; Profumo, Antonella; Quadrelli, Paolo; De Angelis, Filippo; Malavasi, Lorenzo (6 September 2021). "Experimental Strategy and Mechanistic View to Boost the Photocatalytic Activity of Cs₃Bi₂Br₉ Lead-Free Perovskite Derivative by g-C₃N₄ Composite Engineering". Advanced Functional Materials. 31 (46): 2104428. doi:10.1002/adfm.202104428. eISSN 1616-3028. hdl:11584/334481. ISSN 1616-301X.
^ Ghosh, Sirshendu; Mukhopadhyay, SankhaSubhra; Paul, Sumana; Pradhan, Bapi; De, Subodh Kumar (15 October 2020). "Control Synthesis and Alloying of Ambient Stable Pb-Free Cs₃Bi₂Br_9(1–x)I_9x (0 ≤ x ≤ 1) Perovskite Nanocrystals for Photodetector Application". ACS Applied Nano Materials. 3 (11): 11107–11117. doi:10.1021/acsanm.0c02288. eISSN 2574-0970. ISSN 2574-0970. S2CID 228958674.

[1] Tran, Minh N.; Cleveland, Iver J.; Aydil, Eray S. (January 2021). "Physical vapor deposition of the halide perovskite CsBi₂Br₇". Journal of Vacuum Science & Technology A. 39 (1): 013409. Bibcode:2021JVSTA..39a3409T. doi:10.1116/6.0000604. eISSN 1520-8559. ISSN 0734-2101. S2CID 234115452.

[2] Tran, Minh N.; Cleveland, Iver J.; Aydil, Eray S. (2020). "Resolving the discrepancies in the reported optical absorption of low-dimensional non-toxic perovskites, Cs₃Bi₂Br₉ and Cs₃BiBr₆". Journal of Materials Chemistry C. 8 (30): 10456–10463. doi:10.1039/d0tc02783a. eISSN 2050-7534. ISSN 2050-7526. S2CID 225578432.

[3] Terao, Hiromitsu; Ishihara, Hideta; Okuda, Tsutomu; Yamada, Koji; Weiss, Alarich (1 December 1992). "Phase Transition in Cesium Enneabromodibismuthate(III), Cs₃Bi₂Br₉; an ⁸¹Br and ²⁰⁹Bi NQR Study". Zeitschrift für Naturforschung A. 47 (12): 1259–1261. doi:10.1515/zna-1992-1217. eISSN 1865-7109. ISSN 0932-0784. S2CID 197265206.

[4] Timmermans, C. W. M.; Blasse, G. (1 August 1981). "On the Luminescence of Cs₃Bi₂Br₉ Single Crystals". Physica Status Solidi B (in German). 106 (2): 647–655. Bibcode:1981PSSBR.106..647T. doi:10.1002/pssb.2221060230. eISSN 1521-3951. ISSN 0370-1972.

[5] Romani, Lidia; Speltini, Andrea; Dibenedetto, Carlo Nazareno; Listorti, Andrea; Ambrosio, Francesco; Mosconi, Edoardo; Simbula, Angelica; Saba, Michele; Profumo, Antonella; Quadrelli, Paolo; De Angelis, Filippo; Malavasi, Lorenzo (6 September 2021). "Experimental Strategy and Mechanistic View to Boost the Photocatalytic Activity of Cs₃Bi₂Br₉ Lead-Free Perovskite Derivative by g-C₃N₄ Composite Engineering". Advanced Functional Materials. 31 (46): 2104428. doi:10.1002/adfm.202104428. eISSN 1616-3028. hdl:11584/334481. ISSN 1616-301X.

[6] Ghosh, Sirshendu; Mukhopadhyay, SankhaSubhra; Paul, Sumana; Pradhan, Bapi; De, Subodh Kumar (15 October 2020). "Control Synthesis and Alloying of Ambient Stable Pb-Free Cs₃Bi₂Br_9(1–x)I_9x (0 ≤ x ≤ 1) Perovskite Nanocrystals for Photodetector Application". ACS Applied Nano Materials. 3 (11): 11107–11117. doi:10.1021/acsanm.0c02288. eISSN 2574-0970. ISSN 2574-0970. S2CID 228958674.

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